Protonic conduction induced selective room temperature hydrogen response in ZnO/NiO heterojunction surfaces

نویسندگان

چکیده

In this paper, we show that the ionic conduction through surface chemisorbed ambient moisture leads to a remarkably high and selective response towards hydrogen gas at room temperature. The adsorbed water molecules acts as states, due porous granular nature of ZnO nanoparticles 20 ± 5 nm size. This is depicted deviation from Arrhenius behavior near temperatures. further enhanced 5% 71% for 1200 ppm when p-type NiO quasi-nanowires (width 15–20 nm) are mixed with these n-type form homogenous NiO/ZnO nano-bulk p-n heterostructures. maximum obtained about 50–50% composition although it still character which signifies dominance in sensing mechanism. carrier type reversal takes place rather content 60–80% ZnO. parallel current (surface states) has been identified primary factor sensitivity Further, presence heterojunction barriers NiO-ZnO interface along synergistically

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ژورنال

عنوان ژورنال: Sensors and Actuators B-chemical

سال: 2021

ISSN: ['0925-4005', '1873-3077']

DOI: https://doi.org/10.1016/j.snb.2021.130605